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What was the first potion that Snape taught Harry's class to make?

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Final answer:

Professor Snape taught Harry's class to make the Boil-Cure Potion, an introductory lesson in the magical world of Harry Potter.

Step-by-step explanation:

The first potion that Professor Snape taught Harry's class to make in the Harry Potter series was the Boil-Cure Potion. This potion is mentioned in the book "Harry Potter and the Philosopher's Stone", where it is described as an introductory potion that Snape requires his first-year students to brew. Its purpose is to cure boils, and thus it serves as a practical example of how potions can have beneficial effects in the world of Harry Potter.

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