Final answer:
The apical surface of hepatocytes faces the bile canaliculi, while the basolateral surface faces the blood in the form of hepatic sinusoids.
Step-by-step explanation:
The apical surface of hepatocytes faces the bile canaliculi, which are small ducts that collect bile secreted by the hepatocytes. The basolateral surface of hepatocytes faces the blood, specifically the hepatic sinusoids, which are porous blood spaces formed by fenestrated capillaries from nutrient-rich hepatic portal veins and oxygen-rich hepatic arteries. This arrangement allows hepatocytes to process nutrients, toxins, and waste materials from the blood and to secrete bile into the bile canaliculi.