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One mole of a gas occupying 3 dm^3 expands against a constant external pressure of 1 atm to a volume of 13 L. The work done is:

a. 10 atm dm^3
b. 13 atm dm^3
c. 16 atm dm^3
d. 26 atm dm^3

1 Answer

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Final answer:

The work done by a gas that expands from 3 dm^3 to 13 L against a constant external pressure of 1 atm is 10 atm dm^3 (10 L-atm). We find this by using the formula W = -PΔV and taking the negative sign to indicate work done on the gas.

Step-by-step explanation:

The question involves calculating the work done by a gas during an expansion at constant external pressure, a concept from Chemistry. To find the work done, we use the formula:


W = -PΔV

Where:

  • W is the work done by the gas (in liter-atmospheres, L-atm)
  • P is the constant external pressure (in atmospheres, atm)
  • ΔV is the change in volume (in liters, L)

The initial volume (Vi) = 3 dm3 (which is equivalent to 3 L because 1 dm3 = 1 L), final volume (Vf) = 13 L, and constant external pressure (P) = 1 atm. We substitute these values into the formula:


W = -1 atm × (13 L - 3 L)


W = -1 atm × 10 L


W = -10 L-atm

Since work done by the gas is work done against the external pressure, we take the negative sign into account; this indicates work done on the gas. Thus, the work done by the gas during the process is 10 atm dm3 or 10 L-atm.

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