Final answer:
The chemical reaction occurring when NaF is added to disturb the equilibrium of Fe3+(aq) + SCN-(aq) → FeSCN2+(aq) is Fe3+(aq) + SCN-(aq) + NaF(aq) → Fe(SCN)2+(aq) + Na+(aq) + 2F-(aq).
Step-by-step explanation:
To determine the chemical reaction occurring when NaF is added to disturb the equilibrium of Fe3+(aq) + SCN-(aq) → FeSCN2+(aq), you need to gather information from the provided references. In Figure 16.8.1b, it is shown that the addition of thiocyanate ion (SCN-) results in the formation of the red Fe(SCN)2+ ion. In Equation 9.5.7, the net ionic equation is given as 2 Ag+ (aq) + Cr2O7-(aq) → Ag2Cr2O7(s). Therefore, the equation for the reaction when NaF is added to the equilibrium is:
Fe3+(aq) + SCN-(aq) + NaF(aq) → Fe(SCN)2+(aq) + Na+(aq) + 2F-(aq)