Final answer:
The system refers to the specific portion of matter being studied, while the surroundings include everything else in the universe. In the case of the decomposition of H₂O₂, the system includes H₂O₂ itself.
Step-by-step explanation:
The system refers to the specific portion of matter being studied during an experiment, while the surroundings include everything in the universe that is not part of the system. In the case of the decomposition of H₂O₂, the system includes H₂O₂ itself, as it is the substance undergoing the reaction. Therefore, option a is correct.