16.0k views
5 votes
An acid has a pKa value of 4.76. Which of the following is closest to the ratio of concentration of its protonated to deprotonated forms in a pH environment of 6.8?

User Shay Rybak
by
7.7k points

1 Answer

6 votes

Final answer:

Using the Henderson-Hasselbalch equation and given pKa value of 4.76 at pH 6.8, the ratio of the concentration of the deprotonated form to the protonated form of the acid is approximately 110:1.

Step-by-step explanation:

To find the ratio of the concentration of the protonated form to the deprotonated form of an acid in a solution at a particular pH, you can use the Henderson-Hasselbalch equation:

\(\text{pH} = \text{pKa} + \log\left(\frac{[A^-]}{[HA]}\right)\)

Where \(\text{pH}\) is the pH of the solution, \(\text{pKa}\) is the acid dissociation constant, \([A^-]\) is the concentration of the deprotonated form, and \([HA]\) is the concentration of the protonated form. In this case, we know the \(\text{pKa}\) is 4.76 and the \(\text{pH}\) is 6.8. Let's rearrange the equation to solve for the ratio \(\frac{[A^-]}{[HA]}\):

\(\text{pH} - \text{pKa} = \log\left(\frac{[A^-]}{[HA]}\right)\)

\(6.8 - 4.76 = \log\left(\frac{[A^-]}{[HA]}\right)\)

\(2.04 = \log\left(\frac{[A^-]}{[HA]}\right)\)

To find the \(\frac{[A^-]}{[HA]}\) ratio, we calculate \(10^{2.04}\), which gives us approximately 110. Now we can say that the ratio of the deprotonated form to the protonated form of the acid in a pH environment of 6.8 is close to 110:1.

User Illagrenan
by
8.0k points