Final answer:
Methane (CH4) and the perchlorate ion (ClO4−) have a bond angle of approximately 109.5 degrees due to their tetrahedral geometry.
Step-by-step explanation:
Both methane (CH4) and the perchlorate ion (ClO4−) are described as having a tetrahedral geometry. This indicates that their bond angles are approximately 109.5 degrees. This arrangement brings the corners of a tetrahedron further apart compared to a planar arrangement, resulting in bond angles larger than 90 degrees.