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Laundry bleach such as Clorox is a dilute solution of sodium hypochlorite, NaOCl. Write a balanced net ionic equation for the reaction of NaOCl with Na2S2O3:

A. Write the complete chemical equation for the reaction.
B. Identify the spectator ions in the reaction.
C. Balance the net ionic equation.
D. Analyze the role of sodium thiosulfate in the reaction.

1 Answer

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Final answer:

The reaction between sodium hypochlorite and sodium thiosulfate involves sodium hypochlorite as an oxidizing agent and sodium thiosulfate as a reducing agent. Sodium ions are spectator ions, and the net ionic equation must be balanced for charges and atoms. Sodium thiosulfate serves to neutralize chlorine from bleach.

Step-by-step explanation:

The reaction between sodium hypochlorite (NaOCl) and sodium thiosulfate (Na2S2O3) does not have a simple equation because it may proceed through multiple steps and form several intermediate products. However, a simplified version of a possible reaction between them, considering redox processes involved where thiosulfate acts as a reducing agent and hypochlorite as the oxidizing agent, could be represented by the equation:

2 NaOCl(aq) + Na2S2O3(aq) → 2 NaCl(aq) + Na2SO4(aq)

In the above equation, NaOCl acts as an oxidizing agent and sodium thiosulfate as a reducing agent. Looking only at ionic species involved, the sodium ions (Na+) are spectators, meaning they do not participate directly in the reaction. As such, they are not included in the net ionic equation.

To balance the net ionic equation, one needs to ensure that the charges and the number of atoms of each element are equal on both sides of the reaction. This may require adding appropriate coefficients to the reactants and products to achieve this balance.

Finally, the role of sodium thiosulfate in this reaction is to act as a reducing agent, with the sodium hypochlorite acting as an oxidizing agent. In various applications, sodium thiosulfate is used to neutralize chlorine, including the chlorine from bleach, making it useful in dechlorination processes.

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