If you lower the number of air particles surrounding a barely inflated balloon by activating a vacuum pump, the particles of air inside the balloon will start to expand.
This happens because of the difference in air pressure. When the air pressure outside the balloon is reduced by the vacuum pump, the higher pressure inside the balloon pushes against the balloon's walls, causing it to expand.
This is based on the principle of equilibrium in physics, where systems naturally move from areas of high pressure to areas of low pressure until equilibrium is reached. So, in this case, the air inside the balloon is trying to equalize with the lower pressure outside by expanding.
Remember, though, if the pressure difference becomes too great, the balloon can burst. So, always be careful when conducting experiments involving pressure changes