Final answer:
Writing a canonical sum of products—known as an equilibrium constant expression—entails identifying reactants and products, using their concentrations raised to their stoichiometric coefficients in the expression, and excluding solids which are assigned a value of 1.
Step-by-step explanation:
To write a canonical sum of products, also known as the equilibrium constant expression, you follow a specific sequence of steps:
- Identify the reactants and the products in the chemical reaction and write their chemical formulas.
- Refer to the balanced chemical equation and place the arithmetic product of the concentrations of the products (raised to their stoichiometric coefficients) in the numerator.
- Place the product of the concentrations of the reactants (raised to their stoichiometric coefficients) in the denominator.
- If a product or reactant is in a solid state, it is defined to have a value of 1 and thus may not appear in the expression.
For instance, for a reaction A + B → C (solid) + D, where C is solid, the equilibrium expression would look like: [D] / ([A] * [B]). Here, [D] is the concentration of product D, and [A] and [B] are the concentrations of reactants A and B, respectively.
It is also important to understand how to notate products and quotients in scientific notation when dealing with concentrations in a chemical equation.