Final answer:
The Lewis structure of glycine, H₂NCH₂CO₂H, involves attaching the amine group (-NH₂) and the carboxyl group (-CO₂H) to two central carbon atoms and completing the octets for each atom. The geometry around each atom varies from tetrahedral to trigonal planar and bent. Glycine can form different ions in acidic or basic solutions, relevant when considering its behavior in water.
Step-by-step explanation:
The correct Lewis structure for the amino acid glycine, which has the molecular formula H₂NCH₂CO₂H, can be drawn by following these steps:
Place the two carbon atoms in the center with a single bond connecting them.
Attach the amine group (-NH₂) to the left carbon and the carboxyl group (-CO₂H) to the right carbon.
Add two hydrogens to the left carbon (amine-linked carbon) and complete the octets for all atoms except hydrogen, which follows the duet rule.
Ensure there are no charges by checking that each atom has the proper number of bonds (hydrogen forms one bond, oxygen forms two, nitrogen forms three, and carbon forms four).
The local geometry can be predicted by considering the number of bonding electron pairs around each atom; nitrogen has three bonds and one lone pair resulting in a tetrahedral geometry, the central carbon is also tetrahedral, the carbon in the carboxyl group has a trigonal planar geometry, and the oxygen with hydrogen attached in the carboxyl group also has bent geometry due to the two lone pairs on oxygen.
When glycine is dissolved in 1 M HCl, it will form a positively charged cation due to the protonation of the amine group, while in 1 M KOH, glycine will form a negatively charged anion due to the deprotonation of the carboxyl group.
To draw the Lewis structure of glycine in water, consider the acid-base character of the amino acid and the fact that it can zwitterion with a protonated amine group and deprotonated carboxyl group.