Final answer:
The secretion of tears is controlled by the Facial nerve (CN VII), where parasympathetic fibers from this nerve synapse in the pterygopalatine ganglion, then stimulate the lacrimal gland.
Step-by-step explanation:
The secretion of tears by the lacrimal gland is predominantly controlled by the Facial nerve (CN VII). Specifically, the lacrimal gland is innervated by the parasympathetic fibers that originate from the facial nerve. These preganglionic parasympathetic fibers synapse in the pterygopalatine ganglion, and the postganglionic fibers proceed to the lacrimal gland stimulating tear production. This secretion process is an automatic response that is part of the body's parasympathetic nervous system, which manages bodily functions during restful states.