Final answer:
Option B, CuO(s) + SO₃(g) ---> CuSO₄(s), is the reaction for which ?rxn is equal to ?Hf for CuSO₄(s). Since ?rxn is equal to ?Hf, it means that the enthalpy change for this reaction is equal to the standard enthalpy of formation of CuSO₄.
Step-by-step explanation:
The reaction for which ?rxn is equal to ?Hf for CuSO₄(s) is option B, which is CuO(s) + SO₃(g) ---> CuSO₄(s).
This reaction involves the formation of CuSO₄ from CuO and SO₃.
Since ?rxn is equal to ?Hf, it means that the enthalpy change for this reaction is equal to the standard enthalpy of formation of CuSO₄.