Final answer:
The final temperature of a mixture of equal masses of water at 20°C and 80°C will be 50°C, which is the weighted average of the two initial temperatures.
Step-by-step explanation:
When mixing two samples of water at different temperatures, the final temperature of the mixture will be a weighted average of the two initial temperatures, assuming no heat loss to the environment. In the case of a 50.0-g sample of water at 20°C mixed with a 50g sample of water at 80°C, the final temperature would be exactly in the middle of the two starting temperatures, because the masses of the two water samples are equal and water has a specific heat capacity that would not change based on temperature within this range. Therefore, the final temperature of the mixture should be D. 50°C.