Final answer:
Luke 2:14 states that the angels declared 'Glory to God in the highest, and on earth peace, good will toward men,' during the Annunciation to the Shepherds, signifying divine peace bestowed on humanity with the birth of Christ.
Step-by-step explanation:
According to Luke 2:14, the angels declared peace towards men on earth. The verse states, "Glory to God in the highest, and on earth peace, good will toward men." This declaration occurred during the event known as the Annunciation to the Shepherds, where angels announced the birth of Jesus to shepherds in the field, as recorded in the Gospel of Luke. This moment is celebrated and depicted in various forms of Christian art and liturgy. In these portrayals, angels are often shown proclaiming this message of peace and goodwill, which emphasizes the theme of divine peace being bestowed upon humanity with the birth of Christ.