Final answer:
Erwin Chargaff discovered that the base pair composition of DNA follows specific rules - the amount of adenine always equals thymine, and the amount of guanine always equals cytosine. This discovery, known as Chargaff's rules, provided important insights into the structure of DNA.
Step-by-step explanation:
Erwin Chargaff's experiments on the composition of DNA provided important clues about the structure of DNA. He discovered that the amount of adenine (A) always equaled the amount of thymine (T), and the amount of guanine (G) always equaled the amount of cytosine (C) in DNA. This is known as Chargaff's rules. These rules showed that the base pairs in DNA are complementary, with A always pairing with T, and G always pairing with C.