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Which disaccharide does have an anomeric carbon available for oxidation? :

A. Glc (a1⇿1a) GIC
B. Glc (a1 ⇿2β) Fru
C. Fru (β2⇿1a) Glc
D. both Glc (a1⇿2B) Fru and Fru (β2⇿1a) Glc
E. None of the above

User Gizem
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1 Answer

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Final answer:

The disaccharide that has an anomeric carbon available for oxidation is Glc (α1 ⇁2β) Fru. The disaccharide that has an anomeric carbon available for oxidation is sucrose.

Step-by-step explanation:

However, since sucrose is a non-reducing sugar, the correct answer is actually maltose which is a reducing sugar with a free anomeric carbon. This disaccharide, also known as sucrose, has a glucose (Glc) and a fructose (Fru) unit joined by an α1,2-glycosidic linkage.

Since sucrose does not have free anomeric carbons as both are involved in the glycosidic bond, it's actually a non-reducing sugar and does not have an anomeric carbon available for oxidation. Instead, maltose, which contains two glucose units linked by an α1→4 glycosidic linkage, does have an anomeric carbon not involved in the glycosidic linkage and it can open to form an aldehyde group, thus it is a reducing sugar and is the correct answer to the question.

User Rofls
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