Final answer:
To find the expression for the partial derivative (dh/dT) constant S using the Van der Waals equation, we need to differentiate the equation with respect to T, treating S as a constant.
Step-by-step explanation:
To find the expression for the partial derivative ∅(dh/dT) constant S using the Van der Waals equation, we first need to understand the equation itself. The Van der Waals equation is given by:
(P + a/v^2)(v - b) = RT,
where P is the pressure, v is the molar volume, a and b are the Van der Waals constants, R is the universal gas constant, and T is the temperature in Kelvin.
To find the expression for the partial derivative ∅(dh/dT) constant S, we need to differentiate the Van der Waals equation with respect to T, treating S as a constant:
∅(dh/dT) constant S = ∅((P + a/v^2)(v - b))/∅T.
Now, we can simplify and expand the equation to find the derivative.