Final answer:
The equilibrium constant (Kc) for the given reaction A(g) ⇌ B(g) + 2C(g) is approximately 190, calculated using the initial and equilibrium concentrations of A.
Step-by-step explanation:
To calculate the equilibrium constant (Kc) for the reaction A(g) ⇌ B(g) + 2C(g), we need to use the initial and equilibrium concentrations of A. Initially, we have [A] = 0.049 M and at equilibrium [A] = 0.0196 M.
The change in concentration of A, which we'll call 'x', is 0.049 M - 0.0196 M = 0.0294 M. According to the stoichiometry of the reaction, for every 1 mol of A that reacts, 1 mol of B is formed and 2 mol of C are formed.
Thus, the equilibrium concentrations of B and C are [B] = x and [C] = 2x respectively.
Now, the expression for Kc is:
Kc = ([B][C]^2) / [A] = (x)(2x)^2 / (0.0196)
Substituting the value of x = 0.0294 M into this expression, we get:
Kc = (0.0294)(2 * 0.0294)^2 / 0.0196
Upon calculating, the value of Kc is found to be approximately 190.
Therefore, the correct answer is Kc = 190.