Final answer:
All the given statements a through e regarding the quantum numbers that identify an atomic orbital are correct, outlining the rules for the principal, angular momentum, and magnetic quantum numbers as well as the specific cases for s and p orbitals. All the statements are correct.
Step-by-step explanation:
The quantum numbers that identify an atomic orbital include the principal quantum number (n), the angular momentum quantum number (l), and the magnetic quantum number (mℓ). According to quantum mechanics:
- n can be any positive integer and determines the energy level and size of the electron cloud.
- l can have integer values between zero and (n−1) and determines the shape of the orbital.
- mℓ can range from −l to +l in integer steps and determines the orientation of the orbital in space.
- For an s orbital (l=0) of any shell, there is only one possible mℓ value, which is zero.
- For p orbitals (l=1) of any shell, there are three possible mℓ values: −1, 0, +1.
Therefore, based on the provided information, all the statements a through e concerning quantum numbers and atomic orbitals are correct.