Final answer:
The patient's limited ability to extend the right long finger at the proximal interphalangeal joint is most likely caused by extensor adhesions, resulting from scarring and restriction in the extensor tendons after the injury.
Step-by-step explanation:
The most likely cause of the 25-year-old lawyer's inability to extend the right long finger at the proximal interphalangeal joint following a jammed finger after playing basketball, considering X-ray showed a normal articular surface with no fracture or foreign object, is extensor adhesions. Extensor adhesions can occur due to injury or inflammation leading to scarring and restriction in the movement of the tendons responsible for finger extension. Since the patient's flexion is not limited, this suggests that the issue is with the extensor mechanism rather than the flexors.