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Which of the following ions show higher spin only magnetic moment value ?

A. Ti³⁺
B. Mn²⁺
C. Fe³⁺
D. CO³⁺

User Slaus
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1 Answer

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Final answer:

Manganese (II) ions (Mn²⁺) have a high magnetic moment due to their five unpaired electrons, exhibiting a high-spin configuration, which confirms their high magnetic moment value among the given options. The correct answer is option: B. Mn²⁺

Step-by-step explanation:

One of the transition metal ions that shows a higher spin magnetic moment value is Mn²⁺. In the context of transition metals, the magnetic moment is largely determined by the number of unpaired electrons in the d-orbitals of the ion.

For manganese (II) ions, with a d⁵ electron configuration, there are five unpaired electrons, contributing to a high magnetic moment. This is consistent with Mn²⁺ exhibiting a high-spin configuration in most of its complexes. Conversely, ions like Fe³⁺ can show both high and low spin states depending on the ligand field strength.

High-spin complexes have a maximum number of unpaired electrons, therefore a higher magnetic moment, as opposed to low-spin complexes where electrons are paired up whenever possible, resulting in a reduced magnetic moment.

User Tabina
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