Final answer:
To lower the melting point of aluminum oxide, cryolite is added as a solvent in the Hall-Heroult process, enabling electrolysis at around 1000°C.
Step-by-step explanation:
The substance added to lower the melting point of aluminum oxide (â£2Oâ) is cryolite (â£3â£lFâ). In the Hall-Heroult process, a mixture of about 5% aluminum oxide and 95% cryolite is used. Cryolite serves as a solvent and reduces the melting point of the aluminum oxide, thereby allowing it to be electrolyzed at lower temperatures around 1000°C. This process not only decreases energy costs but also facilitates the production of aluminum from its oxide form by electrolysis.