Final answer:
The spectral line of highest wavelength in the Bohr model of the hydrogen atom corresponds to the n = 3 to n = 1 transition. The correct answer is option (a).
Step-by-step explanation:
In the Bohr model of the hydrogen atom, the spectral line of highest wavelength corresponds to the transition from
n = 3 to n = 1.
The Balmer series of emission lines in the hydrogen spectrum is due to transitions from orbits with n ≥ 3 to the orbit with n = 2.
The n = 3 to n = 2 transition gives rise to the line at 656 nm (red), which is the highest wavelength line in the Balmer series.
Therefore, the correct answer is (a) n = 3 to n = 1.