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Which of the following statement(s) is/are correct?

A. For same volume expansion,work done in reversible isothermal process is more as compared to reversible adiabatic process
B. Reversible adiabatic process is also called isentropic process
C. Free expansion is a reversible process
D. If heat is given to a system, then its internal energy must change

1 Answer

3 votes

Final answer:

Statements A and B are correct. Statement A is true because in a reversible isothermal process the system absorbs heat, converting it into work during expansion, which doesn't occur in an adiabatic process. Statement B is true because a reversible adiabatic process maintains constant entropy, making it isentropic. Statements C and D are incorrect; free expansion is not reversible and heat added to a system doesn't necessarily change its internal energy.

Step-by-step explanation:

The question at hand involves understanding different thermodynamic processes and identifying the accuracy of statements related to them. Let's analyze each statement:

A. For the same volume expansion, the work done in a reversible isothermal process is more as compared to a reversible adiabatic process. This is because in a reversible isothermal process, the system is in contact with a heat source and heat is transferred into the system, which the gas converts into work. The adiabatic process does no work as a result of heat transfer because there is none; instead, the work is done at the expense of the gas's internal energy, thus less work is done for the same volume expansion with an adiabatic process.

B. A reversible adiabatic process is also known as an isentropic process. This statement is correct because 'isentropic' means 'constant entropy', and in a reversible adiabatic process, there is no heat transfer and therefore no change in entropy.

C. Free expansion is not a reversible process because it involves rapid expansion without any external work done, often against a vacuum, and thus cannot be reversed simply by reversing the process's direction.

D. If heat is given to a system, then its internal energy may change, but it is not a must. The change in internal energy also depends on the work done by or on the system, so it is possible for a system to absorb heat without changing its internal energy, such as in an isothermal process for an ideal gas.

Therefore, the correct statements are A and B.

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