Final answer:
The number of moles of ac- in the student's solution D before a reaction took place is 0.05452 moles.
Step-by-step explanation:
To find the number of moles of ac- in the student's solution D before a reaction took place, we need to use the information given. The student prepared a 1:1 buffer where the concentration of ac- and hac is 0.05452 M. When the student mixed the 1:1 buffer with a 0.09811 M NaOH solution, a reaction took place. In the reaction, the NaOH reacts with the hac to form ac- ions. Since the NaOH is in excess, all of the hac is reacted. Therefore, before the reaction took place, the number of moles of ac- in the solution D would be equal to the number of moles of ac- in the 1:1 buffer, which is 0.05452 moles.