Final answer:
To find the spacing between the planes of the crystal, Bragg's Law is used with the given X-ray wavelength and the observed angle of the first interference maximum. The same law then allows us to find the angle at which the second maximum will be observed.
Step-by-step explanation:
The question involves using Bragg's Law, which relates the angle of incident X-rays to the spacing between crystal planes. The first strong interference maximum, or first-order diffraction, occurs when the path difference is equal to the wavelength (nλ = 2d sin θ), where n=1. Given the X-ray wavelength is 0.240 nm, and the first maximum is observed at an angle of 21.0°, we can find the spacing, d, using the Bragg equation:
1×0.240 nm = 2d sin(21.0°)
We can rearrange this to solve for d:
d = (1×0.240 nm) / (2 sin(21.0°))
Once we have the value of d, the second-order maximum will be for n=2. We can then solve for the second angle, θ2, using the same Bragg equation:
2×0.240 nm = 2d sin(θ2)
Rearranging for θ2:
sin(θ2) = (2×0.240 nm) / (2d)
And then calculating the inverse sine to find the angle.