Final answer:
The Little Devil's Postpile is a basalt plug featuring weathered columnar joints, formed from quick cooling and contracting lava.
Step-by-step explanation:
The Little Devil's Postpile is a basalt plug, remnant of a volcanic conduit, that has been weathered into columnar joints. This unique geological formation is created when lava cools and contracts quickly, leading to the development of polygonal columns, typically in a hexagonal pattern.
Such features are also commonly found in other volcanic areas around the world and are representative of the type of igneous activity that shapes our planet's landscape.