Final answer:
The reaction demonstrating heterogeneous equilibrium is PbCl2(s) ⇌ Pb²⁺(aq) + 2Cl⁻(aq).
Step-by-step explanation:
The reaction that demonstrates heterogeneous equilibrium is option b) PbCl2(s) ⇌ Pb²⁺(aq) + 2Cl⁻(aq). In this reaction, the reactant PbCl2 is in the solid state, while the products Pb²⁺ and Cl⁻ are in the aqueous state. Heterogeneous equilibrium occurs when the reactants and products are in different phases or states.