Final answer:
In the AD-AS model, an outward shift of a country's PPF is best demonstrated by a rightward shift of the long-run aggregate supply (LRAS) curve, indicating increased productive potential.
Step-by-step explanation:
An outward shift of a country's Production Possibility Frontier (PPF) would indicate that the country has increased its capacity to produce goods and services. In the context of the AD-AS model (Aggregate Demand-Aggregate Supply model), this increase in productive capacity would be best represented by option D: The long-run aggregate supply (LRAS) curve shifts rightward. This shift illustrates that at every price level, the economy can now produce a greater quantity of real GDP because of productivity improvements or an increase in the factors of production such as technology or capital. Such a shift signals potential for economic growth, and it typically results in lower unemployment and lower inflation as the economy can produce more without increasing prices significantly.