Final answer:
RNA molecules can have tertiary and quaternary structure due to their secondary structure allowing for interactions that produce these structures, unlike DNA molecules.
Step-by-step explanation:
RNA molecules can have tertiary and quaternary structure because they have a secondary structure that leaves bases free for interactions that produce tertiary and quaternary structure.
On the other hand, DNA molecules do not have tertiary and quaternary structure because their secondary structure does not allow for such interactions. The complementary base pairing in RNA allows the formation of three-dimensional structures, while DNA lacks this feature.