Final answer:
The item that does not fit the pattern among atmosphere, biosphere, cryosphere, geosphere, and lithosphere is the biosphere, as it uniquely represents areas supporting life and overlaps with aspects of the other spheres mentioned.
Step-by-step explanation:
The question asks which of the following does not fit the pattern: atmosphere, biosphere, cryosphere, geosphere, lithosphere. The biosphere is the correct answer because it is the only one of the options that represents the areas of the Earth that support plant and animal life, including the air, land, surface rocks, and water. The atmosphere is the gaseous layer surrounding Earth, the cryosphere represents the frozen water part of the Earth, the geosphere refers to the solid parts of Earth, such as rocks and soils, and the lithosphere is the rigid outer layer of the Earth, including the crust and upper mantle. However, the biosphere is unique as it encompasses aspects of all the other spheres where life exists.