Final answer:
The ΔEN values determine the nature of the K-Br and Au-Br bonds.
Step-by-step explanation:
The difference in electronegativity (ΔEN) between two bonded atoms can determine the type of bond and the behavior of a substance. In general, as the ΔEN increases, the bond becomes more polar and the substance exhibits different properties. In the case of the K-Br bond with a ΔEN of 2.0, it is expected to be more ionic in nature. On the other hand, the Au-Br bond with a ΔEN of 0.4 is expected to be more covalent in nature.