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What elements in this reaction get oxidized and reduced?

Cr₂O₇⁻² (aq) + C₂O₄⁻² (aq) = Cr⁺³(aq) +CO₂ (g)

Cr = +6
O = -2
C = +3
O = -2
Cr = +3
C = +4
O = -2

1 Answer

4 votes

Final answer:

Chromium is reduced from +6 to +3, and carbon is oxidized from +3 to +4 in the provided chemical reaction, which takes place in a basic solution.

Step-by-step explanation:

In the given reaction Cr₂O₇²⁻ (aq) + C₂O₄²⁻ (aq) = Cr⁺³(aq) + CO₂ (g), we can identify the elements that are oxidized and reduced by analyzing the changes in their oxidation states. Chromium (Cr) is reduced since its oxidation state decreases from +6 in Cr₂O₇²⁻ to +3 in Cr⁺³(aq). Carbon (C) is oxidized as its oxidation state increases from +3 in C₂O₄²⁻ to +4 in CO₂.

Reduction: Cr₂O₇²⁻ (aq) + 14H+ (aq) + 6e⁻ → 2Cr⁺³ (aq) + 7H₂O (l)

Oxidation: C₂O₄²⁻ (aq) → 2CO₂ (g) + 2e⁻

The overall reaction occurs in a basic solution where the balance of atoms and charge is maintained with the addition of OH⁻ as opposed to H+ ions.

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