Final answer:
Hydrochloric acid reacts with the benzoate ion to form benzoic acid, which precipitates out of the solution.
Step-by-step explanation:
The correct answer is c. Hydrochloric acid reacted with the benzoate ion to make benzoic acid. When aqueous hydrochloric acid is added to the combined aqueous layers that were drained out of the separatory funnel while recovering separated benzoic acid, the hydrochloric acid reacts with the benzoate ion present in the solution. This reaction forms benzoic acid, which is insoluble in water and precipitates out of the solution.