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"Which fact is most important in explaining why cellulose is a better structural material than starch?

A. Alpha-linkages make it easier for the polymer to coil into a helix which is worse for structural use.
B. Branched polymers can form more hydrogen bonds than unbranched polymers.
C. Links between alpha glucoses are stronger than links between beta glucoses.
D. Polymers made of fructose are stronger than polymers made of glucose.
E. C-C links are stronger than C-O-C links."

User Gorros
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Final Answer:

C. Links between alpha glucoses are stronger than links between beta glucoses.

Step-by-step explanation:

Cellulose and starch are both polysaccharides composed of glucose units, but the key difference lies in the type of glycosidic linkages between these glucose units. Cellulose consists of β-1,4-glycosidic linkages, while starch is made up of α-1,4-glycosidic linkages. The orientation of these linkages plays a crucial role in determining the structural properties of the polymers.

The correct answer is C because β-linkages in cellulose are more stable and resistant than α-linkages in starch. The angle and position of the glycosidic linkage in cellulose allow for stronger intermolecular hydrogen bonding between adjacent chains. These bonds contribute to the formation of a highly stable, linear structure in cellulose, making it a better structural material than the more branched and helical structure of starch.

In cellulose, the β-linkages create a linear chain with a high degree of hydrogen bonding, forming strong, rigid fibers. This structural integrity is essential in providing strength and support to plant cell walls. In contrast, the α-linkages in starch result in a more coiled structure, which is less conducive to the formation of a robust and stable framework. Therefore, the type of glycosidic linkage, specifically the stronger nature of β-linkages, is the most critical factor in explaining why cellulose surpasses starch as a superior structural material.

User Kumaresh Babu N S
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