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12.50 g of a hydrated form of copper(II) sulfate, CuSO4•x H2O (where x is unknown) is gently heated. When all the water has been driven off, the mass of the anhydrous copper(II) sulfate is found to be 7.99 g. What is the mass of the water that was lost as a result of the heating?

A. Convert this mass of water to moles of water.
B. Convert the mass of the anhydrous CuSO4 to moles. Divide the answer to b by the answer to c. This is the value of x in the formula of the hydrate. Write the formula of hydrated copper(II) sulfate.

1 Answer

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Final answer:

The mass of water lost from the hydrated copper(II) sulfate after heating is 4.51 g. This corresponds to approximately 0.250 moles of water. After calculating the moles of anhydrous CuSO4, we find that x, the number of water molecules per formula unit of CuSO4, is 5, resulting in the formula CuSO4·5H2O for the hydrated compound.

Step-by-step explanation:

To find the mass of the water that was lost due to heating, we subtract the mass of the anhydrous copper(II) sulfate from the original mass of the hydrated copper(II) sulfate. Thus:

  • Mass of hydrated copper(II) sulfate: 12.50 g
  • Mass of anhydrous copper(II) sulfate: 7.99 g
  • Mass of water lost = 12.50 g - 7.99 g = 4.51 g

To convert the mass of water to moles, we use the molar mass of water (H2O), which is 18.015 g/mol:

Moles of water = Mass of water / Molar mass of H2O = 4.51 g / 18.015 g/mol ≈ 0.250 moles

Next, we convert the mass of anhydrous CuSO4 to moles. We use the molar mass of CuSO4, which is approximately 159.61 g/mol:

Moles of CuSO4 = Mass of anhydrous CuSO4 / Molar mass of CuSO4 = 7.99 g / 159.61 g/mol ≈ 0.050 moles

Now we can find the value of x, the number of moles of water per mole of anhydrous CuSO4:

x = Moles of water / Moles of anhydrous CuSO4 = 0.250 moles / 0.050 moles = 5

Therefore, the hydrated form of copper(II) sulfate is CuSO4·5H2O, known as copper(II) sulfate pentahydrate.

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