Final answer:
The rate constant (k) for the first-order reaction is calculated as 3.9 x 10^-2 s^-1, considering two significant digits.
Step-by-step explanation:
The question asks us to calculate the rate constant (k) for a first-order reaction where the rate is given as 1.5 x 10-2 M/s when the concentration of A is 0.38 M. For a first-order reaction, the rate law is expressed as rate = k[A], where [A] is the concentration of the reactant. Re-arranging this formula to solve for the rate constant gives us k = rate / [A].
Plugging in the values from the question:
k = (1.5 x 10-2 M/s) / (0.38 M)
k = 0.03947 s-1
Now, keeping in mind the correct number of significant digits, we get:
k = 3.9 x 10-2 s-1 (to two significant digits)
The units of the rate constant for a first-order reaction are s-1, which align with the answer above.