Final answer:
The quickest means of telling apart K2SO4 and BaSO4 is to add LiNO3 solution to each. Ba(NO3)2 will precipitate from BaSO4, indicating its presence.
Step-by-step explanation:
The quickest means of telling apart K2SO4 and BaSO4 is to add LiNO3 solution to each. Ba(NO3)2 will precipitate from BaSO4, indicating its presence. This is because BaSO4 is insoluble in water while K2SO4 is soluble. The net ionic equation for this reaction is: Ba²+ (aq) + SO² (aq) → BaSO4(s).