Final answer:
The Potassium - Argon system is used for dating rocks based on the decay of potassium into argon. The Potassium - Calcium system is not used for dating because of various reasons.
Step-by-step explanation:
The Potassium - Argon system is used for dating nonorganic materials such as rocks because the decay of potassium into argon can be measured. Potassium-40 decays by positron emission and electron capture to form Argon-40 with a half-life of 1.25 billion years. The age of a rock can be determined by measuring the amount of Argon-40 gas that escapes from the rock sample.
In contrast, Potassium - Calcium system is not used for dating because:
- 40Ca derived from Potassium cannot be distinguished from the existing 40Ca in the environment.
- Calcium cannot be measured by a mass spectrometer.
- Calcium is lost under pressure.
- Calcium is a larger atom compared to Argon, making it more difficult to measure accurately.