Final answer:
The volume of KMnO₄ added during the titration is 23.24 mL.
Step-by-step explanation:
To determine the volume of KMnO₄ added during the titration, we need to subtract the initial volume reading from the final volume reading of the buret. The initial reading of the solution in the buret is 0.00 mL, and the final reading is 23.24 mL. So, the volume of KMnO₄ added during the titration is 23.24 mL - 0.00 mL = 23.24 mL.