Final answer:
Chlorine (Cl) reacts with potassium (K) to form potassium chloride (KCl), a salt where both ions are isoelectronic with argon.
Step-by-step explanation:
The element that reacts with potassium to form a salt, has relatively high ionization energy, and is isoelectronic with argon is chlorine (Cl). Chlorine has an atomic number of 17, and once it gains an electron, it forms a chloride ion (Cl-) with an electron configuration the same as argon (18 electrons in total).
Potassium (K), with an atomic number of 19, will lose one electron to form a potassium ion (K+), which also has 18 electrons and is thus isoelectronic with argon. This ionic exchange results in an ionic compound known as potassium chloride (KCl), a typical salt.