Final answer:
The appropriate control structure for this scenario is an if-else statement.
Step-by-step explanation:
The appropriate control structure that can be used to examine the value of the floating-point variable temp and print the corresponding message is an if-else statement. Here is an example:
if (temp < 0) {
printf("ICE");
} else if (temp <= 100) {
printf("WATER");
} else {
printf("STEAM");
}
Since we need to evaluate multiple conditions, a switch statement is not suitable for this instance. Switch statements are typically used when we have a single value to compare against multiple constant values.