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A gas in a rigid container has a pressure of 3.5 atm at 200. k. calculate the pressure at 273k. volume remains constant.

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Final answer:

The pressure of a gas at a new temperature of 273K, when initially it has a pressure of 3.5 atm at 200K, can be calculated using Gay-Lussac's Law. The new pressure is found to be approximately 4.78 atm when the volume remains constant.

Step-by-step explanation:

The question involves calculating the change in pressure of a gas when its temperature is increased while keeping its volume constant, based on the principles of ideal gas law. According to Gay-Lussac's Law, which states that the pressure of a gas is directly proportional to its absolute temperature when the volume is held constant, the new pressure can be calculated using the formula:

P1/T1 = P2/T2

Where:

  • P1 is the initial pressure (3.5 atm)
  • T1 is the initial temperature (200K)
  • P2 is the final pressure
  • T2 is the final temperature (273K)

By rearranging the equation and solving for P2, we can determine the new pressure:

P2 = P1 · (T2/T1)

P2 = 3.5 atm · (273K / 200K) = 3.5 atm · 1.365 = 4.7775 atm

The new pressure at 273K with constant volume is then approximately 4.78 atm.

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