Final answer:
To calculate the heat of the reaction, we need to determine the heat absorbed by the water and the bomb in a bomb calorimeter. Once we have the values for qwater and qbomb, the heat of the reaction can be calculated using the equation ΔH = -qwater - qbomb.
Step-by-step explanation:
When a 5.000 g sample of methanol, CH3OH, is combusted in the presence of excess oxygen in a bomb calorimeter containing 4000 g of water, the temperature of the water increases from 20.000 to 29.765 °C. The heat capacity of the calorimeter is 26571/°C and the specific heat of water is 4.184 J/g °C. To calculate the heat of the reaction, we need to determine the heat absorbed by the water and the bomb.
- Heat absorbed by water: qwater = mass of water × specific heat of water × temperature change
- Heat absorbed by the bomb: qbomb = heat capacity of the bomb calorimeter × temperature change
Once we have the values for qwater and qbomb, the heat of the reaction can be calculated using the equation:
ΔH = -qwater - qbomb