Final answer:
The sigma bond between the central As atom and the outer F atom in hexafluoroarsenate ion is formed by the overlap of an sp³ d² hybrid orbital on the central As atom and an atomic orbital on the outer F atom.
Step-by-step explanation:
The sigma bond between the central As atom and the outer F atom in hexafluoroarsenate ion (AsF6-) is formed by the overlap of an sp³ d² hybrid orbital on the central As atom and an atomic orbital on the outer F atom.