Final answer:
The density of the perfume is 0.416 g/mL, which is less dense than water with a density of 1.00 g/mL, making option (b) the correct answer.
Step-by-step explanation:
To calculate the density of the perfume, we first need to find the mass of the perfume alone. We do this by subtracting the mass of the empty graduated cylinder from the combined mass. So, the mass of the perfume is 68.8 g - 58.4 g = 10.4 g. Density is mass divided by volume. Therefore, the density of the perfume = (10.4 g) / (25.0 mL) = 0.416 g/mL.
The density of water is 1.00 g/mL. Since the perfume's density (0.416 g/mL) is less than the density of water, the perfume is less dense than water.
Hence, the correct answer is (b) 0.416 g/mL, less dense than water.