Final answer:
The polar molecule between HBr and Br2 is HBr, as it contains a polar covalent bond between hydrogen and bromine, which have different electronegativities. Br2 is non-polar due to the identical nature of the bromine atoms resulting in a symmetrical molecule.
Step-by-step explanation:
To determine which molecule is polar between HBr (hydrogen bromide) and Br2 (dibromine), we can look at the symmetry of the molecule and the electronegativity of the atoms involved. A polar molecule has a distribution of electric charge leading to one end being slightly positive and the other end being slightly negative, resulting in a molecule with a dipole moment. In diatomic molecules, polarity arises when the two atoms have different electronegativities. In the case of HBr, hydrogen and bromine have different electronegativities which results in a polar covalent bond and thus a polar molecule. Br2, however, is a molecule composed of two identical bromine atoms; therefore, it is non-polar due to its symmetrical nature and equal electronegativities of the bromine atoms.
The correct answer to the given question is option 'a': The polar molecule is HBr because it has a positive and negative end. Br2 is non-polar because it's symmetrical and the atoms have the same electronegativity.