Final answer:
Benjamin Franklin was a member of the Committee of Five and played a key role in establishing an alliance with the French during the American Revolution, making him the correct answer to the question posed.
Step-by-step explanation:
The individual who served on the Committee of Five and helped create an alliance with the French is Benjamin Franklin. Franklin was a notable figure during the American Revolution, serving as an inventor, diplomat, and statesman. He was instrumental in drafting the Declaration of Independence as a member of the Committee, alongside John Adams, Roger Sherman, Robert Livingston, and Thomas Jefferson.
Moreover, Franklin's tenure as the U.S. Ambassador to France was crucial in securing French support for the American cause, which was a significant factor in the success of the American Revolution. Therefore, the answer to the student's question is A) Benjamin Franklin.