Final answer:
A block of metal heated from 25°C to 150°C will expand due to thermal expansion.
Step-by-step explanation:
When a block of metal is heated from 25°C to 150°C, the metal expands in size. This is due to thermal expansion, a phenomenon where the kinetic energy of atoms and molecules increases with temperature, causing them to move apart and the material to expand. As for fitting a metal peg into a hole in another metal block, the block should be hotter than the peg during insertion to allow for expansion of the hole and contraction of the peg upon cooling, ensuring a tight fit.